Contamination,bioaccessibility and human health risk of heavy metals in exposed-lawn soils from 28 urban parks in southern China's largest city,Guangzhou     

《Applied Geochemistry》2016

The total concentrations and oral bioaccessibility of heavy metals in surface-exposed lawn soils from 28 urban parks in Guangzhou were investigated, and the health risks posed to humans were evaluated. The descending order of total heavy metal concentrations was Fe > Mn > Pb > Zn > Cu > Cr > Ni > Cd, but Cd showed the highest percentage bioaccessibility (75.96%). Principal component analysis showed that Grouped Cd, Pb, Cr, Ni, Cu and Zn, and grouped Cr and Mn could be controlled two different types of human sources. Whereas, Ni and Fe were controlled by both anthropogenic and natural sources. The carcinogenic risk probabilities for Pb and Cr to children and adults were under the acceptable level (<1 × 10⁻⁴). Hazard Quotient value for each metal and Hazard Index values for all metals studied indicated no significant risk of non-carcinogenic effects to children and adults in Guangzhou urban park soils.  相似文献   

云南富宁县水合口矿化蚀变信息提取和找矿预测     

刘峰  朱杰勇  白光顺  孙滨 《矿产与地质》2016,(3):450-454

云南富宁水合口金矿位于滇东南文山―富宁成矿带,属于著名的滇黔桂"金三角"地区。利用landsat 8OLI遥感影像对研究区进行1∶100 000矿化蚀变信息提取,结合区域地质和化探异常等多元信息进行找矿预测,表明矿化蚀变、断裂构造交汇处和地球化学异常空间叠加部位为有利找矿地区,圈定了5个找矿远景区,为研究区开展下一步找矿提供了科学依据。  相似文献   

低电压偶极地电提取装置在广西昭平古袍金矿区试验效果     

胡云沪  徐熙  张青伟  马慧宇 《矿产与地质》2016,(4):669-673

通过在广西昭平古袍金矿区已知矿体上方进行的低电压偶极地电提取装置地电提取试验研究,显示阴极提取和阳极提取在已知矿体上方都获取到了清晰的地电提取异常。在矿头位置,阳极提取量比阴极提取量要大,而在矿体隐伏端,阴极的异常特别明显。阳极与阴极提取量之间几乎没有相关性。将阴离子与阳离子累加能更加清晰地指示出矿体的位置。说明地电提取测量法在广西大瑶山古袍金矿区寻找隐伏金矿是可行的,并且用偶极地电提取装置寻找隐伏金矿效果会更好。  相似文献   

高位定向钻孔在综放工作面上隅角瓦斯抽采中的应用          下载免费PDF全文

段会军  郝世俊  武建军 《探矿工程》2016,43(10):215-218

针对王家岭煤矿综放工作面瓦斯涌出量大、上隅角瓦斯超限的问题,使用定向钻机及机具,利用定向钻进技术进行高位定向钻孔瓦斯抽放。在分析工作面回采过程中瓦斯运移规律的基础上,通过大量现场实践,得出适用于该矿区的高位定向钻孔轨迹布设参数,有效地解决了上隅角瓦斯超限问题,实现高瓦斯矿井工作面安全高效开采。  相似文献   

遥感技术在内蒙古东乌珠穆沁旗萨麦地区的找矿应用     

贺瑾瑞  陈国浒  张翊超  宋庆伟 《城市地质》2016,(4):99-105

本文以内蒙古东乌珠穆沁旗萨麦地区1:5万巴彦塔拉等4幅区域地质调查范围为研究区,以ETM+影像数据为信息源,以波谱理论为基础,从遥感图像中提取蚀变信息继而进行遥感找矿实践。针对区内铁染、羟基蚀变类型使用主成分分析等方法,将研究区划分为10个异常区,结合区域构造特征情况,对异常区域开展了1:1万路线调查,综合判定后,选择了4个找矿靶区进行了化探剖面探测并进行了成果分析,结果显示遥感蚀变信息与野外调查和化探异常吻合较好。  相似文献   

Experimental and theoretical study of a cylindrical oscillating water column device with a quadratic power take-off model     

《Applied Ocean Research》2016

The wave power extraction by a cylindrical oscillating water column (OWC) device with a quadratic power take-off (PTO) model was studied experimentally and theoretically. In the experiment, a scaled model OWC was tested in a wave flume, with an orifice being used to simulate a quadratic PTO mechanism. In the theoretical analysis, the quadratic PTO model was linearized based on Lorenz's principle of equivalent work, which allows us to perform a frequency domain analysis using an eigen-function matching method. The effects of higher harmonic components and the spatial non-uniformity of the surface velocity inside the chamber were discussed. A semi-analytical model was proposed to understand the viscous loss affecting the measured capture length. Our treatment of the quadratic PTO model was validated by comparing quasi-linear theoretical capture length and the laboratory measurement. Our results also showed that the effects of spatial non-uniformity and viscous loss could be noticeable for shorter waves.  相似文献   

胶州湾沉积物重金属形态不同浸取方法的比较与污染讯息指示作用初探   总被引：1，自引：0，他引：1  

梁宪萌  宋金明  段丽琴  袁华茂  李宁  李学刚 《海洋学报》2016,38(10):12-21

海洋沉积物中重金属的活性形态对于指示沉积物污染状况具有重要作用;为探寻简洁且能够有效提取重金属活性形态的浸提方法;实验研究了0.1 mol/L和1 mol/L盐酸的单级提取和欧共体标准局（European Community Bureau of Reference）提出的BCR分级提取法对胶州湾表层沉积物中重金属（Cr、Cu、Ni、Pb、Zn）和Al、Fe、Mn的浸取效果。结果显示;3种提取方法提取的金属含量呈显著正相关关系;两种浓度的稀盐酸对BCR方法中的酸可提取态和可还原态金属均具有较好浸提效果;但对可氧化态金属浸提能力相对较弱。不同提取方法的人为信号指数（ASI）计算结果表明;BCR浸取法提取结果的金属ASI值最大;表明其对沉积物中金属活性形态提取效率较高;1 mol/L HCl提取结果的金属ASI值最低;可能是较高浓度强酸使沉积物较大颗粒内层中“惰性”金属被浸取出来;“增加”了金属活性组分的污染讯息信号;对沉积物中Cu、Pb和Zn而言;0.1 mol/L HCl提取结果的ASI值与BCR方法接近。经过Al归一化后;0.1 mol/L HCl浸提的重金属含量的空间分布与胶州湾的实际污染状况相吻合;表明0.1 mol/L的HCl在一定程度上能够代替复杂的BCR浸取法;此方法可简化重金属活性形态的提取步骤;适合大范围沉积物重金属污染评价。  相似文献   

利用监督分类快速提取分层设色图件中数据的方法     

刘晓  黄海军  孙荣涛  张照录  宋明春  董慧君 《海洋科学》2016,40(7):110-114

为了快速将分层设色图件中象元的颜色值转化为具有实际意义的属性标识或物理、化学参数值,从而提取分层设色图件中包含的数据,作者提出了根据不同颜色分量(RGB)构建颜色特征空间,基于最小距离监督分类方法快速提取分层设色图件中数据的方法。使用该方法对东半球海域海面水汽分布数据进行提取,取得了良好的效果。该方法可以广泛应用于物理海洋、环境科学、地质调查、地理信息系统建库等多个行业领域的数据提取工作中。  相似文献   

绿藻水溶性多糖的研究概况和进展   总被引：1，自引：0，他引：1  

李莎兰  洪亮  李诚博  刘晨光 《海洋科学》2016,40(9):145-151

对近年来绿藻多糖的提纯方法、组成结构及应用的研究进展进行了综述。绿藻多糖的提纯需要经过样品的前处理、提取和精制三个步骤,提取方法包括酸提、酶提、加入钙螯合剂提取、微波及超声波辅助提取。绿藻多糖是水溶性的硫酸化杂多糖。从石莼(Ulva)、浒苔(Enteromorpha)、礁膜(Monostroma)、小球藻(Chlorella)、蕨菜(Bracken)及刚毛藻(Bristles)中提取的多糖的化学组成及结构特征各不相同,而且多糖的化学组成和结构特征受提取方式的影响。绿藻多糖的生物相容性、生物可降解性及抗氧化、抗肿瘤、抗凝血、抗炎、免疫调节等多种生物活性使其在食品、医药、化妆品及农业中具有广泛的应用。有关绿藻多糖的精确结构、提纯方法及化学修饰的进一步研究将使绿藻多糖的应用更加广泛。  相似文献   

Copper Speciation in a Collection of Geochemical Reference Materials Using Sequential Extraction and Evaluation of the Validity Using XANES Spectroscopy          下载免费PDF全文

Atsuyuki Ohta  Ran Kubota 《Geostandards and Geoanalytical Research》2016,40(1):117-134

Copper speciation in a collection of Japanese geochemical reference materials (JSO‐1, JLk‐1, JSd‐1, ‐2, ‐3 and ‐4, JMs‐1 and JMs‐2) was achieved by sequential extraction and characterised using X‐ray absorption near‐edge structure spectroscopy. In the first step of the extraction, referred to as the acid fraction, between 1% and 20% total Cu within the reference materials was extracted. Such a result is typically accounted for by absorption of Cu onto clay minerals. However, the presence of Cu sulfate (an oxidation product of chalcopyrite) was observed in some of the stream sediments affected by mining activity (JSd‐2 and JSd‐3) instead. Copper was extracted in the reducible fraction (targeting Fe hydroxide and Mn oxide) (2–49% total Cu). Between 2% and 51% Cu was extracted in the oxidised fraction (targeting sulfides and organic matter). X‐ray absorption near‐edge structure spectroscopy clarified that the reducible fraction consisted of Cu bound to Fe hydroxide, whereas the oxidised fraction was a mixture of Cu bound to humic acid (HA) and Cu sulfide. In the oxidisable fraction, chalcopyrite was the predominant species identified in JSd‐2, and Cu bound to HA was the major species identified in JSO‐1 (a soil sample).  相似文献